Characterization of Reactive Intermediates by Multinuclear Diffusion-Ordered NMR Spectroscopy (DOSY)
نویسندگان
چکیده
منابع مشابه
High Resolution Diffusion-Ordered Spectroscopy (HR-DOSY)
This application note demonstrates the utility of the DOSY package in the VnmrJ 3.1 software for both 2D and 3D HR-DOSY analysis of complex mixtures, by first elucidating the presence of two components in an epoxy mixture (2D), and then proving that a minority component in a protein mixture was in fact a smaller derivative of the major component (3D).
متن کاملHigh Resolution Diffusion-Ordered Spectroscopy (HR-DOSY)
This application note demonstrates the utility of the DOSY package in the VnmrJ 3.1 software for both 2D and 3D HR-DOSY analysis of complex mixtures, by first elucidating the presence of two components in an epoxy mixture (2D), and then proving that a minority component in a protein mixture was in fact a smaller derivative of the major component (3D).
متن کاملSingle-scan 2D DOSY NMR spectroscopy.
Spatial encoding is a particular kind of spin manipulation that enables the acquisition of multidimensional NMR spectra within a single scan. This encoding has been shown to possess a general applicability and to enable the completion of arbitrary nD NMR acquisitions within a single transient. The present study explores its potential towards the acquisition of 2D DOSY spectra, where the indirec...
متن کاملDiffusion Coefficient-Formula Weight Correlation Analysis via Diffusion-Ordered Nuclear Magnetic Resonance Spectroscopy (DOSY NMR) To Examine Acylglycerol Mixtures and Biodiesel Production
Biodiesel, fatty acid methyl esters derived from vegetable oils, is a well-established alternative to petroleum diesel. We have developed a rapid H diffusion-ordered nuclear magnetic resonance spectroscopy (DOSY NMR)method to resolve mixtures of mono-, di-, and triacyglycerols alongwith their methyl esters. Because of the differences in diffusion coefficients between the starting materials (tri...
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ژورنال
عنوان ژورنال: Accounts of Chemical Research
سال: 2008
ISSN: 0001-4842,1520-4898
DOI: 10.1021/ar800127e